{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 9)"],"submitter":["Chen J"],"pubmed_abstract":["In the title complex, [Co(C(12)H(8)N(2))(3)][CoI(C(12)H(8)N(2))(2)(H(2)O)][Bi(3)I(12)], conventionally abbreviated [Co(phen)(3)][CoI(phen)(2)(H(2)O)][Bi(3)I(12)], where phen is 1,10-phenanthroline, the Co(II) atom in one cation is coordinated by six N atoms from three phen ligands in an octa-hedral coordination while the Co(II) atom in the other cation is coordinated octa-hedrally by four N atoms from two phen ligands, one water O atom and one I atom. In the anion, three Bi(III) ions adopt an octa-hedral coordination constructed by six I(-) ligands. The three BiI(6) octa-hedra are fused together through trans face-sharing."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1284-5"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200835"],"repository":["biostudies-literature"],"pubmed_title":["A double salt of iodo-bis-muthate: cis-aqua-iodidobis(1,10-phenanthroline)cobalt(II) tris-(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa-iodidotribismuthate(III)."],"pmcid":["PMC3200835"],"pubmed_authors":["Song L","Yang Y","Chen J","Niu F","Chai W"],"additional_accession":[]},"is_claimable":false,"name":"A double salt of iodo-bis-muthate: cis-aqua-iodidobis(1,10-phenanthroline)cobalt(II) tris-(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa-iodidotribismuthate(III).","description":"In the title complex, [Co(C(12)H(8)N(2))(3)][CoI(C(12)H(8)N(2))(2)(H(2)O)][Bi(3)I(12)], conventionally abbreviated [Co(phen)(3)][CoI(phen)(2)(H(2)O)][Bi(3)I(12)], where phen is 1,10-phenanthroline, the Co(II) atom in one cation is coordinated by six N atoms from three phen ligands in an octa-hedral coordination while the Co(II) atom in the other cation is coordinated octa-hedrally by four N atoms from two phen ligands, one water O atom and one I atom. In the anion, three Bi(III) ions adopt an octa-hedral coordination constructed by six I(-) ligands. The three BiI(6) octa-hedra are fused together through trans face-sharing.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Sep","modification":"2025-04-04T08:06:20.945Z","creation":"2019-03-26T23:59:26Z"},"accession":"S-EPMC3200835","cross_references":{"pubmed":["22058879"],"doi":["10.1107/S1600536811033460"]}}