<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 9)</volume><submitter>Yu RJ</submitter><pubmed_abstract>A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa-hedron distorted by Jahn-Teller effects. Inter-molecular O-H⋯O, O-H⋯N, N-H⋯O and N-H⋯N hydrogen-bonding inter-actions link these units into a three-dimensional supra-molecular architecture.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1253</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200852</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN]bis-(nitrato-κO)copper(II).</pubmed_title><pmcid>PMC3200852</pmcid><pubmed_authors>Deng B</pubmed_authors><pubmed_authors>Yu RJ</pubmed_authors></additional><is_claimable>false</is_claimable><name>Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN]bis-(nitrato-κO)copper(II).</name><description>A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa-hedron distorted by Jahn-Teller effects. Inter-molecular O-H⋯O, O-H⋯N, N-H⋯O and N-H⋯N hydrogen-bonding inter-actions link these units into a three-dimensional supra-molecular architecture.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Sep</publication><modification>2025-04-04T08:06:25.259Z</modification><creation>2019-03-26T23:59:28Z</creation></dates><accession>S-EPMC3200852</accession><cross_references><pubmed>22064322</pubmed><doi>10.1107/S1600536811032399</doi></cross_references></HashMap>