{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 9)"],"submitter":["Win YF"],"pubmed_abstract":["The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal-bipyramidal geometry by two monodentate carboxyl-ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl-ate groups [O-Sn-O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitro-benzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter-molecular N-H⋯O and weak C-H⋯O inter-actions into a three-dimensional network. The crystal structure is further stabilized by weak inter-molecular C-H⋯π inter-actions."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1276-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200871"],"repository":["biostudies-literature"],"pubmed_title":["catena-Poly[[triphenyl-tin(IV)]-μ-5-amino-2-nitro-benzoato-κO:O]."],"pmcid":["PMC3200871"],"pubmed_authors":["Fun HK","Teoh SG","Quah CK","Choong CS","Win YF"],"additional_accession":[]},"is_claimable":false,"name":"catena-Poly[[triphenyl-tin(IV)]-μ-5-amino-2-nitro-benzoato-κO:O].","description":"The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal-bipyramidal geometry by two monodentate carboxyl-ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl-ate groups [O-Sn-O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitro-benzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter-molecular N-H⋯O and weak C-H⋯O inter-actions into a three-dimensional network. The crystal structure is further stabilized by weak inter-molecular C-H⋯π inter-actions.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Sep","modification":"2025-04-04T08:06:28.993Z","creation":"2019-03-26T23:59:28Z"},"accession":"S-EPMC3200871","cross_references":{"pubmed":["22064934"],"doi":["10.1107/S1600536811033332"]}}