biostudies-literatureUnknown67(Pt 9)Wang ZMThe title compound, C(15)H(9)BrN(2)S, was prepared by the reaction of 1-bromo-2-(2,2-dibromo-vin-yl)benzene with 1H-benzo[d]imidazole-2(3H)-thione. The thia-zolo[3,2-a]benz-imidazole fused-ring system is nearly planar, the maximum atomic deviation being 0.049 (4) Å. This mean plane is oriented at a dihedral angle of 71.55 (17)° with respect ot the bromo-phenyl ring. π-π stacking is observed in the crystal structure, the centroid-centroid distance between the thia-zole and imidazole rings of adjacent mol-ecules being 3.582 (2) Å.Acta crystallographica. Section E, Structure reports onlineo2540https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200872biostudies-literature3-(2-Bromo-phen-yl)thia-zolo[3,2-a]benzimidazole.PMC3200872Wang ZMYu BCui YZhang XQSun XQfalse3-(2-Bromo-phen-yl)thia-zolo[3,2-a]benzimidazole.The title compound, C(15)H(9)BrN(2)S, was prepared by the reaction of 1-bromo-2-(2,2-dibromo-vin-yl)benzene with 1H-benzo[d]imidazole-2(3H)-thione. The thia-zolo[3,2-a]benz-imidazole fused-ring system is nearly planar, the maximum atomic deviation being 0.049 (4) Å. This mean plane is oriented at a dihedral angle of 71.55 (17)° with respect ot the bromo-phenyl ring. π-π stacking is observed in the crystal structure, the centroid-centroid distance between the thia-zole and imidazole rings of adjacent mol-ecules being 3.582 (2) Å.2011-01-01T00:00:00Z2011 Sep2025-04-04T08:06:29.287Z2019-03-27T00:01:07ZS-EPMC32008722206502210.1107/S1600536811034842