<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 9)</volume><submitter>Rehman J</submitter><pubmed_abstract>The title compound, C(10)H(14)N(2)O(3)S, crystallized with two mol-ecules (A and B) in the asymmetric unit. The terminal methyl group of the ethyl-sulfonamide moiety in mol-ecule B is disordered over two sets of sites with an occupancy ratio of 0.61 (1):0.39 (1). Both mol-ecules have L-shaped conformations. In mol-ecule A, the dihedral angles between the benzene ring and its ethyl-sulfonamide and methyl-amide substituents are 83.5 (3) and 13.34 (18)°, respectively. Equivalent values for mol-ecule B are 87.9 (3) and 6.32 (16)°, respectively. The C-S-N-C torsion angles are 66.5 (3)° for A and -64.4 (3)° for B, indicating similar twists about the S-N bonds, but in opposite senses. In the crystal, the A mol-ecules are linked by pairs of N(s)-H⋯O (s = sulfonamide) hydrogen bonds, generating inversion dimers containing R(2) (2)(8) rings, while the B mol-ecules are linked by N(s)-H⋯O hydrogen bonds into C(10) [100] chains. Finally, N(a)-H⋯O (a = amide) hydrogen bonds link the A-mol-ecule dimers and B-mol-ecule chains into a three-dimensional network.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o2455</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200875</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>N-[4-(Ethyl-sulfamo-yl)phen-yl]acetamide.</pubmed_title><pmcid>PMC3200875</pmcid><pubmed_authors>Rehman J</pubmed_authors><pubmed_authors>Harrison WT</pubmed_authors><pubmed_authors>Farid S</pubmed_authors><pubmed_authors>Khan IU</pubmed_authors><pubmed_authors>Ejaz</pubmed_authors></additional><is_claimable>false</is_claimable><name>N-[4-(Ethyl-sulfamo-yl)phen-yl]acetamide.</name><description>The title compound, C(10)H(14)N(2)O(3)S, crystallized with two mol-ecules (A and B) in the asymmetric unit. The terminal methyl group of the ethyl-sulfonamide moiety in mol-ecule B is disordered over two sets of sites with an occupancy ratio of 0.61 (1):0.39 (1). Both mol-ecules have L-shaped conformations. In mol-ecule A, the dihedral angles between the benzene ring and its ethyl-sulfonamide and methyl-amide substituents are 83.5 (3) and 13.34 (18)°, respectively. Equivalent values for mol-ecule B are 87.9 (3) and 6.32 (16)°, respectively. The C-S-N-C torsion angles are 66.5 (3)° for A and -64.4 (3)° for B, indicating similar twists about the S-N bonds, but in opposite senses. In the crystal, the A mol-ecules are linked by pairs of N(s)-H⋯O (s = sulfonamide) hydrogen bonds, generating inversion dimers containing R(2) (2)(8) rings, while the B mol-ecules are linked by N(s)-H⋯O hydrogen bonds into C(10) [100] chains. Finally, N(a)-H⋯O (a = amide) hydrogen bonds link the A-mol-ecule dimers and B-mol-ecule chains into a three-dimensional network.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Sep</publication><modification>2025-04-04T08:06:30.157Z</modification><creation>2019-03-26T23:59:28Z</creation></dates><accession>S-EPMC3200875</accession><cross_references><pubmed>22059023</pubmed><doi>10.1107/S1600536811033472</doi></cross_references></HashMap>