{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 9)"],"submitter":["Ling C"],"pubmed_abstract":["In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra-hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra-molecular C-H⋯N hydrogen bonds are observed."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1232-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3200904"],"repository":["biostudies-literature"],"pubmed_title":["Tris(1,10-phenanthroline)iron(II) μ-oxido-bis-[trichloridoferrate(III)]."],"pmcid":["PMC3200904"],"pubmed_authors":["Song L","Ling C","Wang X"],"additional_accession":[]},"is_claimable":false,"name":"Tris(1,10-phenanthroline)iron(II) μ-oxido-bis-[trichloridoferrate(III)].","description":"In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra-hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra-molecular C-H⋯N hydrogen bonds are observed.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Sep","modification":"2025-04-04T08:06:36.651Z","creation":"2019-03-26T23:59:28Z"},"accession":"S-EPMC3200904","cross_references":{"pubmed":["22065697"],"doi":["10.1107/S1600536811031783"]}}