<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 10)</volume><submitter>Li CQ</submitter><pubmed_abstract>In the crystal structure of the title coordination polymer, {[Zn(2)(C(17)H(8)O(10))(C(3)H(7)NO)(2)]·C(3)H(7)NO}(n), the mol-ecular build-ing block (MBB), viz. {Zn(2)(CO(2))(4)(C(3)H(7)NO)(2)}, comprises two zinc atoms, each bridged by three carboxyl-ate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal-pyramidal, and square-pyramidal formed by the two coordinated dimethyl-formamide mol-ecules and three carboxylate groups, and a distorted tetra-hedral coordination defined by carboxy-late groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1406</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201252</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Poly[[bis-(dimethyl-formamide)[μ(7)-5,5'-(methyl-enedi-oxy)diisophthalato]dizinc] dimethyl-formamide monosolvate].</pubmed_title><pmcid>PMC3201252</pmcid><pubmed_authors>Qiu WG</pubmed_authors><pubmed_authors>He H</pubmed_authors><pubmed_authors>Li CQ</pubmed_authors></additional><is_claimable>false</is_claimable><name>Poly[[bis-(dimethyl-formamide)[μ(7)-5,5'-(methyl-enedi-oxy)diisophthalato]dizinc] dimethyl-formamide monosolvate].</name><description>In the crystal structure of the title coordination polymer, {[Zn(2)(C(17)H(8)O(10))(C(3)H(7)NO)(2)]·C(3)H(7)NO}(n), the mol-ecular build-ing block (MBB), viz. {Zn(2)(CO(2))(4)(C(3)H(7)NO)(2)}, comprises two zinc atoms, each bridged by three carboxyl-ate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal-pyramidal, and square-pyramidal formed by the two coordinated dimethyl-formamide mol-ecules and three carboxylate groups, and a distorted tetra-hedral coordination defined by carboxy-late groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Oct</publication><modification>2025-04-04T08:05:50.487Z</modification><creation>2019-03-26T23:59:29Z</creation></dates><accession>S-EPMC3201252</accession><cross_references><pubmed>22064841</pubmed><doi>10.1107/S1600536811037056</doi></cross_references></HashMap>