{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 10)"],"submitter":["Li KK"],"pubmed_abstract":["The unit cell of the title compound, [Mn(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·C(10)H(8)N(2), consists of a binuclear cation, two perchlor-ate anions, and one solvent 2,2'-bipyridine (bpy) mol-ecule. In the complex cation [Mn(2)(C(2)O(4))(C(10)N(2)H(8))(4)](2+), two Mn(II) atoms are bridged by a bis-(bidentate) oxalate ligand, each Mn(II) atom being further coordinated by two bpy ligands in a distorted octa-hedral geometry. The distance between the two six-coordinated metal atoms is 5.583 (1) Å. π-π stacking inter-actions [inter-planar distances between bpy rings = 3.739 (1) Å] are essential to the supramolecular assembly. There are extensive inter-ionic C-H⋯O inter-actions between the cations and between the cation and anion. Three of the four perchlorate O atoms are disordered over "],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1443-4"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201320"],"repository":["biostudies-literature"],"pubmed_title":["μ-Oxalato-bis-[bis-(2,2'-bipyridine)-manganese(II)] bis(perchlorate) 2,2'-bipyridine solvate."],"pmcid":["PMC3201320"],"pubmed_authors":["Li KK","Zhang C","Xu W"],"additional_accession":[]},"is_claimable":false,"name":"μ-Oxalato-bis-[bis-(2,2'-bipyridine)-manganese(II)] bis(perchlorate) 2,2'-bipyridine solvate.","description":"The unit cell of the title compound, [Mn(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·C(10)H(8)N(2), consists of a binuclear cation, two perchlor-ate anions, and one solvent 2,2'-bipyridine (bpy) mol-ecule. In the complex cation [Mn(2)(C(2)O(4))(C(10)N(2)H(8))(4)](2+), two Mn(II) atoms are bridged by a bis-(bidentate) oxalate ligand, each Mn(II) atom being further coordinated by two bpy ligands in a distorted octa-hedral geometry. The distance between the two six-coordinated metal atoms is 5.583 (1) Å. π-π stacking inter-actions [inter-planar distances between bpy rings = 3.739 (1) Å] are essential to the supramolecular assembly. There are extensive inter-ionic C-H⋯O inter-actions between the cations and between the cation and anion. Three of the four perchlorate O atoms are disordered over ","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Oct","modification":"2025-04-19T06:09:34.118Z","creation":"2019-03-26T23:59:29Z"},"accession":"S-EPMC3201320","cross_references":{"pubmed":["22058714"],"doi":["10.1107/S1600536811038475"]}}