{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 10)"],"submitter":["De Lorentiis L"],"pubmed_abstract":["The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](-) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (-), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter-act only through a weak inter-action between the Cl atom of the anion and an H atom of a phenyl ring of the cation."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1356"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201402"],"repository":["biostudies-literature"],"pubmed_title":["Bis(triphenyl-phosphanyl-idene)iminium dichloridotriphenyl-stannate(IV)."],"pmcid":["PMC3201402"],"pubmed_authors":["De Lorentiis L","Graiff C","Predieri G"],"additional_accession":[]},"is_claimable":false,"name":"Bis(triphenyl-phosphanyl-idene)iminium dichloridotriphenyl-stannate(IV).","description":"The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](-) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (-), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter-act only through a weak inter-action between the Cl atom of the anion and an H atom of a phenyl ring of the cation.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Oct","modification":"2025-04-04T08:05:55.229Z","creation":"2019-03-26T23:59:30Z"},"accession":"S-EPMC3201402","cross_references":{"pubmed":["22065826"],"doi":["10.1107/S1600536811035422"]}}