biostudies-literatureUnknown67(Pt 10)De Lorentiis LThe structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](-) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (-), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter-act only through a weak inter-action between the Cl atom of the anion and an H atom of a phenyl ring of the cation.Acta crystallographica. Section E, Structure reports onlinem1356https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201402biostudies-literatureBis(triphenyl-phosphanyl-idene)iminium dichloridotriphenyl-stannate(IV).PMC3201402De Lorentiis LGraiff CPredieri GfalseBis(triphenyl-phosphanyl-idene)iminium dichloridotriphenyl-stannate(IV).The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](-) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (-), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter-act only through a weak inter-action between the Cl atom of the anion and an H atom of a phenyl ring of the cation.2011-01-01T00:00:00Z2011 Oct2025-04-04T08:05:55.229Z2019-03-26T23:59:30ZS-EPMC32014022206582610.1107/S1600536811035422