{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 10)"],"submitter":["Lee JP"],"pubmed_abstract":["The homoleptic thio-ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa-kis-(thio-ether) octa-hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia-cyclo-nona-ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (-) anions present to balance the charge, and each shows disorder along a pseudo-C(3) axis with ratios of 0.53 (2):0.47 (2) and 0.55 (2):0.45 (2). Two nitro-methane solvent mol-ecules per complex cation are also present in the unit cell."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1417-8"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201448"],"repository":["biostudies-literature"],"pubmed_title":["Bis(1,4,7-trithia-cyclo-nona-ne)nickel(II) bis-(tetra-fluorido-borate) nitro-methane disolvate."],"pmcid":["PMC3201448"],"pubmed_authors":["Noll BC","Grant GJ","Lee JP"],"additional_accession":[]},"is_claimable":false,"name":"Bis(1,4,7-trithia-cyclo-nona-ne)nickel(II) bis-(tetra-fluorido-borate) nitro-methane disolvate.","description":"The homoleptic thio-ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa-kis-(thio-ether) octa-hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia-cyclo-nona-ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (-) anions present to balance the charge, and each shows disorder along a pseudo-C(3) axis with ratios of 0.53 (2):0.47 (2) and 0.55 (2):0.45 (2). Two nitro-methane solvent mol-ecules per complex cation are also present in the unit cell.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Oct","modification":"2025-04-04T08:06:11.108Z","creation":"2019-03-26T23:59:30Z"},"accession":"S-EPMC3201448","cross_references":{"pubmed":["22064382"],"doi":["10.1107/S1600536811037809"]}}