{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 10)"],"submitter":["Li FA"],"pubmed_abstract":["In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H⋯Cl hydrogen bonds. Intra-molecular O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.5958 (16) Å] are also present."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1366"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3201524"],"repository":["biostudies-literature"],"pubmed_title":["Bis(μ-3-chloro-benzene-1,2-dicarboxyl-ato-κO:O)bis-[diaqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)]."],"pmcid":["PMC3201524"],"pubmed_authors":["Li FA","Hu XM","Xu F"],"additional_accession":[]},"is_claimable":false,"name":"Bis(μ-3-chloro-benzene-1,2-dicarboxyl-ato-κO:O)bis-[diaqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)].","description":"In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H⋯Cl hydrogen bonds. Intra-molecular O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.5958 (16) Å] are also present.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Oct","modification":"2025-04-04T08:06:20.979Z","creation":"2019-03-26T23:59:30Z"},"accession":"S-EPMC3201524","cross_references":{"pubmed":["22058694"],"doi":["10.1107/S1600536811035112"]}}