<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 12)</volume><submitter>Datta A</submitter><pubmed_abstract>In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu-Cl distance of 2.4655 (7) Å. Inter-molecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Formula: see text]].</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1852</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3238746</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Dichlorido{N'-[(pyridin-2-yl)methyl-idene-κN]acetohydrazide-κN',O}copper(II).</pubmed_title><pmcid>PMC3238746</pmcid><pubmed_authors>Huang JH</pubmed_authors><pubmed_authors>Datta A</pubmed_authors><pubmed_authors>Sheu SC</pubmed_authors><pubmed_authors>Liu PH</pubmed_authors></additional><is_claimable>false</is_claimable><name>Dichlorido{N'-[(pyridin-2-yl)methyl-idene-κN]acetohydrazide-κN',O}copper(II).</name><description>In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu-Cl distance of 2.4655 (7) Å. Inter-molecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Formula: see text]].</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Dec</publication><modification>2025-04-26T16:51:56.013Z</modification><creation>2019-03-27T00:01:09Z</creation></dates><accession>S-EPMC3238746</accession><cross_references><pubmed>22199623</pubmed><doi>10.1107/S1600536811049671</doi></cross_references></HashMap>