biostudies-literatureUnknown67(Pt 12)Semenaka VVThe heterometallic title complex, [Cr(2)Mn(2)(C(5)H(11)NO(2))(2)(C(5)H(12)NO(2))(2)(NCS)(4)]·4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thio-cyanate and a non-aqueous solution of N-methyl-diethano-lamine in air. The centrosymmetric mol-ecular structure of the complex is based on a tetra-nuclear {Mn(2)Cr(2)(?-O)(6)} core. The tetra-nuclear complex mol-ecule and the two uncoordinated dimethyl-formamide mol-ecules are linked by O-H?O hydrogen bonds, while the two other mol-ecules of dimethyl-formamide do not participate in hydrogen bonding.Acta crystallographica. Section E, Structure reports onlinem1864-5https://www.ebi.ac.uk/biostudies/studies/S-EPMC3238755biostudies-literatureBis{?(2)-2-[(2-hy-droxy-eth-yl)(meth-yl)amino]-ethano-lato}bis-(?(3)-N-methyl-2,2'-aza-nediyldiethano-lato)tetra-kis-(thio-cyan-atato-?N)dichromium(III)dimanganese(II) dimethyl-formamide tetra-solvate.PMC3238755Semenaka VVKokozay VNZubatyuk RIShishkin OVNesterova OVfalseBis{?(2)-2-[(2-hy-droxy-eth-yl)(meth-yl)amino]-ethano-lato}bis-(?(3)-N-methyl-2,2'-aza-nediyldiethano-lato)tetra-kis-(thio-cyan-atato-?N)dichromium(III)dimanganese(II) dimethyl-formamide tetra-solvate.The heterometallic title complex, [Cr(2)Mn(2)(C(5)H(11)NO(2))(2)(C(5)H(12)NO(2))(2)(NCS)(4)]·4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thio-cyanate and a non-aqueous solution of N-methyl-diethano-lamine in air. The centrosymmetric mol-ecular structure of the complex is based on a tetra-nuclear {Mn(2)Cr(2)(?-O)(6)} core. The tetra-nuclear complex mol-ecule and the two uncoordinated dimethyl-formamide mol-ecules are linked by O-H?O hydrogen bonds, while the two other mol-ecules of dimethyl-formamide do not participate in hydrogen bonding.2011-01-01T00:00:00Z2011 Dec2021-03-14T08:51:36Z2019-03-26T23:59:33ZS-EPMC32387552219963210.1107/S1600536811049336