<HashMap><database>biostudies-literature</database><scores><citationCount>0</citationCount><reanalysisCount>0</reanalysisCount><viewCount>49</viewCount><searchCount>0</searchCount></scores><additional><omics_type>Unknown</omics_type><volume>67(Pt 11)</volume><submitter>Fan Z</submitter><pubmed_abstract>The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio-carbazate and 2-bromo-4,5-dimeth-oxy-benzaldehyde. In the mol-ecule, the benzene ring and dithio-carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The dithio-carbazate fragment is approximately planar (r.m.s deviation = 0.0281 Å) and the mean plane is oriented at a dihedral angle of 11.38 (15)° with respect to the benzene ring. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o2919</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3247333</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Methyl (E)-3-(2-bromo-4,5-dimeth-oxy-benzyl-idene)dithio-carbazate.</pubmed_title><pmcid>PMC3247333</pmcid><pubmed_authors>Huang YW</pubmed_authors><pubmed_authors>Fan Z</pubmed_authors><pubmed_authors>Huang YL</pubmed_authors><pubmed_authors>Tong F</pubmed_authors><pubmed_authors>Shan S</pubmed_authors><view_count>49</view_count></additional><is_claimable>false</is_claimable><name>Methyl (E)-3-(2-bromo-4,5-dimeth-oxy-benzyl-idene)dithio-carbazate.</name><description>The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio-carbazate and 2-bromo-4,5-dimeth-oxy-benzaldehyde. In the mol-ecule, the benzene ring and dithio-carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The dithio-carbazate fragment is approximately planar (r.m.s deviation = 0.0281 Å) and the mean plane is oriented at a dihedral angle of 11.38 (15)° with respect to the benzene ring. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Nov</publication><modification>2024-12-04T11:54:57.96Z</modification><creation>2019-03-27T00:01:10Z</creation></dates><accession>S-EPMC3247333</accession><cross_references><pubmed>22219951</pubmed><doi>10.1107/S1600536811039304</doi></cross_references></HashMap>