{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 1)"],"submitter":["Kant R"],"pubmed_abstract":["In the centrosymmetric title compound, [Cd(2)(C(13)H(12)NOS(2))(4)], pairs of dithio-carbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one Cd(II) atom and forms a planar four-membered CS(2)Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring Cd(II) atoms, forming extended eight-membered C(2)S(4)Cd(2) tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the Cd(II) atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8)."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m12-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3254292"],"repository":["biostudies-literature"],"pubmed_title":["Bis(μ-N-benzyl-N-furfuryldithio-carbamato)-1:2κS,S':S';2:1κS,S':S'-bis-[(N-benzyl-N-furfuryldithio-carbamato-κS,S')cadmium]."],"pmcid":["PMC3254292"],"pubmed_authors":["Kapoor K","Thirumaran S","Kant R","Valarmathi P","Gupta VK"],"additional_accession":[]},"is_claimable":false,"name":"Bis(μ-N-benzyl-N-furfuryldithio-carbamato)-1:2κS,S':S';2:1κS,S':S'-bis-[(N-benzyl-N-furfuryldithio-carbamato-κS,S')cadmium].","description":"In the centrosymmetric title compound, [Cd(2)(C(13)H(12)NOS(2))(4)], pairs of dithio-carbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one Cd(II) atom and forms a planar four-membered CS(2)Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring Cd(II) atoms, forming extended eight-membered C(2)S(4)Cd(2) tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the Cd(II) atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Jan","modification":"2025-04-26T21:39:48.204Z","creation":"2019-03-27T00:01:10Z"},"accession":"S-EPMC3254292","cross_references":{"pubmed":["22259320"],"doi":["10.1107/S1600536811051348"]}}