<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 2)</volume><submitter>Banu NA</submitter><pubmed_abstract>In the title compound, C(24)H(20)N(2)O(5)S·C(3)H(7)NO, a benzene ring is positioned axially to the pyrimidine ring, which adopts a twist-boat conformation, and is inclined to its mean plane by 85.36?(7)°. In the crystal, inter-molecular C-H?O inter-actions result in centrosymmetric head-to-head dimers with an R(2) (2)(14) graph-set motif along the b axis. Pairs of C-H?O and O-H?O hydrogen bonds form centrosymmetric head-to-head dimers about inversion centres, corresponding to an R(2) (2)(7) graph-set motif along the a axis.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o441</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3275196</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Ethyl 2-(4-carb-oxy-benzyl-idene)-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-thia-zolo[3,2-a]pyrimidine-6-carboxyl-ate-N,N-dimethyl-formamide (1/1).</pubmed_title><pmcid>PMC3275196</pmcid><pubmed_authors>Banu NA</pubmed_authors><pubmed_authors>Bheema Raju V</pubmed_authors></additional><is_claimable>false</is_claimable><name>Ethyl 2-(4-carb-oxy-benzyl-idene)-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-thia-zolo[3,2-a]pyrimidine-6-carboxyl-ate-N,N-dimethyl-formamide (1/1).</name><description>In the title compound, C(24)H(20)N(2)O(5)S·C(3)H(7)NO, a benzene ring is positioned axially to the pyrimidine ring, which adopts a twist-boat conformation, and is inclined to its mean plane by 85.36?(7)°. In the crystal, inter-molecular C-H?O inter-actions result in centrosymmetric head-to-head dimers with an R(2) (2)(14) graph-set motif along the b axis. Pairs of C-H?O and O-H?O hydrogen bonds form centrosymmetric head-to-head dimers about inversion centres, corresponding to an R(2) (2)(7) graph-set motif along the a axis.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Feb</publication><modification>2021-02-20T19:08:29Z</modification><creation>2019-03-26T23:59:38Z</creation></dates><accession>S-EPMC3275196</accession><cross_references><pubmed>22347052</pubmed><doi>10.1107/S1600536812000050</doi></cross_references></HashMap>