{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 4)"],"submitter":["Ravoof TB"],"pubmed_abstract":["In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C-H⋯N hydrogen-bonding inter-actions."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m390-1"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343804"],"repository":["biostudies-literature"],"pubmed_title":["Bis{S-benzyl 3-[(phen-yl)(pyridin-2-yl)methyl-idene]dithio-carbazato}zinc acetonitrile monosolvate."],"pmcid":["PMC3343804"],"pubmed_authors":["Crouse KA","Mohamed Tahir MI","Omar SA","Ravoof TB"],"additional_accession":[]},"is_claimable":false,"name":"Bis{S-benzyl 3-[(phen-yl)(pyridin-2-yl)methyl-idene]dithio-carbazato}zinc acetonitrile monosolvate.","description":"In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C-H⋯N hydrogen-bonding inter-actions.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Apr","modification":"2025-04-04T09:11:50.327Z","creation":"2019-03-27T00:53:02Z"},"accession":"S-EPMC3343804","cross_references":{"pubmed":["22589778"],"doi":["10.1107/S1600536812009592"]}}