biostudies-literatureUnknown68(Pt 4)Ravoof TBIn the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C-H⋯N hydrogen-bonding inter-actions.Acta crystallographica. Section E, Structure reports onlinem390-1https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343804biostudies-literatureBis{S-benzyl 3-[(phen-yl)(pyridin-2-yl)methyl-idene]dithio-carbazato}zinc acetonitrile monosolvate.PMC3343804Crouse KAMohamed Tahir MIOmar SARavoof TBfalseBis{S-benzyl 3-[(phen-yl)(pyridin-2-yl)methyl-idene]dithio-carbazato}zinc acetonitrile monosolvate.In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C-H⋯N hydrogen-bonding inter-actions.2012-01-01T00:00:00Z2012 Apr2025-04-04T09:11:50.327Z2019-03-27T00:53:02ZS-EPMC33438042258977810.1107/S1600536812009592