{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 4)"],"submitter":["Yin X"],"pubmed_abstract":["The title compound, {[Co(3)(C(6)H(4)NO(2))(2)(C(8)H(3)NO(6))(2)(H(2)O)(2)]·4H(2)O}(n), exhibits a two-dimensional layer-like structure in which the Co(II) ions exhibit two kinds of coordination geometries. One nearly octa-hedral Co(II) ion with crystallographic inversion symmetry is coordinated to six carboxyl-ate O atoms from four bridging 5-nitro-isophthalate (NIPH) ligands and two isonicotinate (IN) anions, while the other type of Co(II) ion binds with one N atom and one carboxyl-ate O atom from two IN anions, two carboxyl-ate O atoms from two different NIPH anions and one ligated water mol-ecule, displaying a distorted square-pyramidal coordination geometry. Three adjacent Co(II) ions are bridged by six carboxyl-ate groups from four NIPH ligands and two IN anions to form a linear trinu"],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m451-2"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343849"],"repository":["biostudies-literature"],"pubmed_title":["Poly[[diaqua-bis-[μ(4)-5-nitro-isophthalato-κ(4)O(1):O(1):O(3):O(3')]bis-[μ(3)-pyridine-4-carboxyl-ato-κ(3)O:O':N]tricobalt(II)] tetra-hydrate]."],"pmcid":["PMC3343849"],"pubmed_authors":["Zhang W","Yin X","Fan J","Zheng S","Xin J"],"additional_accession":[]},"is_claimable":false,"name":"Poly[[diaqua-bis-[μ(4)-5-nitro-isophthalato-κ(4)O(1):O(1):O(3):O(3')]bis-[μ(3)-pyridine-4-carboxyl-ato-κ(3)O:O':N]tricobalt(II)] tetra-hydrate].","description":"The title compound, {[Co(3)(C(6)H(4)NO(2))(2)(C(8)H(3)NO(6))(2)(H(2)O)(2)]·4H(2)O}(n), exhibits a two-dimensional layer-like structure in which the Co(II) ions exhibit two kinds of coordination geometries. One nearly octa-hedral Co(II) ion with crystallographic inversion symmetry is coordinated to six carboxyl-ate O atoms from four bridging 5-nitro-isophthalate (NIPH) ligands and two isonicotinate (IN) anions, while the other type of Co(II) ion binds with one N atom and one carboxyl-ate O atom from two IN anions, two carboxyl-ate O atoms from two different NIPH anions and one ligated water mol-ecule, displaying a distorted square-pyramidal coordination geometry. Three adjacent Co(II) ions are bridged by six carboxyl-ate groups from four NIPH ligands and two IN anions to form a linear trinu","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Apr","modification":"2025-04-04T09:12:08.307Z","creation":"2019-03-27T00:53:02Z"},"accession":"S-EPMC3343849","cross_references":{"pubmed":["22589823"],"doi":["10.1107/S1600536812011269"]}}