{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 4)"],"submitter":["Kim YI"],"pubmed_abstract":["In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolate ligands within a distorted tetra-hedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O-H⋯O hydrogen bonds link the complex mol-ecules to the methanol solvent mol-ecules."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m504-5"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343889"],"repository":["biostudies-literature"],"pubmed_title":["Bis(2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolato-κ(2)N,O)zinc methanol disolvate."],"pmcid":["PMC3343889"],"pubmed_authors":["Kim DY","Kim YI","Yun SJ","Hwang IH","Kang SK"],"additional_accession":[]},"is_claimable":false,"name":"Bis(2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolato-κ(2)N,O)zinc methanol disolvate.","description":"In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolate ligands within a distorted tetra-hedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O-H⋯O hydrogen bonds link the complex mol-ecules to the methanol solvent mol-ecules.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Apr","modification":"2025-04-04T09:11:42.64Z","creation":"2019-03-27T00:53:03Z"},"accession":"S-EPMC3343889","cross_references":{"pubmed":["22589857"],"doi":["10.1107/S160053681201272X"]}}