{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 4)"],"submitter":["Meyer-Wegner F"],"pubmed_abstract":["The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017]."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m507"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343891"],"repository":["biostudies-literature"],"pubmed_title":["trans-Dichloridobis(triphenyl-phosphane-κP)palladium(II) benzene hemisolvate."],"pmcid":["PMC3343891"],"pubmed_authors":["Bolte M","Sinke T","Meyer-Wegner F","Lerner HW"],"additional_accession":[]},"is_claimable":false,"name":"trans-Dichloridobis(triphenyl-phosphane-κP)palladium(II) benzene hemisolvate.","description":"The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017].","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Apr","modification":"2025-04-04T09:11:43.079Z","creation":"2019-03-27T00:53:02Z"},"accession":"S-EPMC3343891","cross_references":{"pubmed":["22589859"],"doi":["10.1107/S1600536812012494"]}}