biostudies-literatureUnknown68(Pt 4)Meyer-Wegner FThe title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017].Acta crystallographica. Section E, Structure reports onlinem507https://www.ebi.ac.uk/biostudies/studies/S-EPMC3343891biostudies-literaturetrans-Dichloridobis(triphenyl-phosphane-κP)palladium(II) benzene hemisolvate.PMC3343891Bolte MSinke TMeyer-Wegner FLerner HWfalsetrans-Dichloridobis(triphenyl-phosphane-κP)palladium(II) benzene hemisolvate.The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017].2012-01-01T00:00:00Z2012 Apr2025-04-04T09:11:43.079Z2019-03-27T00:53:02ZS-EPMC33438912258985910.1107/S1600536812012494