<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 5)</volume><submitter>Ha K</submitter><pubmed_abstract>In the title complex, trans-[PtCl(2)(C(9)H(7)N)(2)], the Pt(II) ion is four-coordinated in an essentially square-planar coordination environment defined by two N atoms from two quinoline (qu) ligands and two Cl(-) anions. The Pt atom is located on an inversion centre and thus the asymmetric unit contains one half of the complex; the PtN(2)Cl(2) unit is exactly planar. The dihedral angle between the PtN(2)Cl(2) unit and the quinoline ligand is 85.1 (1)°. In the crystal, the complex mol-ecules are stacked into columns along the b axis. In the columns, several inter-molecular π-π inter-actions between the six-membered rings are present, the shortest ring centroid-centroid distance being 3.733 (5) Å between pyridine rings.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m536</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344296</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>trans-Dichloridobis(quinoline-κN)platinum(II).</pubmed_title><pmcid>PMC3344296</pmcid><pubmed_authors>Ha K</pubmed_authors></additional><is_claimable>false</is_claimable><name>trans-Dichloridobis(quinoline-κN)platinum(II).</name><description>In the title complex, trans-[PtCl(2)(C(9)H(7)N)(2)], the Pt(II) ion is four-coordinated in an essentially square-planar coordination environment defined by two N atoms from two quinoline (qu) ligands and two Cl(-) anions. The Pt atom is located on an inversion centre and thus the asymmetric unit contains one half of the complex; the PtN(2)Cl(2) unit is exactly planar. The dihedral angle between the PtN(2)Cl(2) unit and the quinoline ligand is 85.1 (1)°. In the crystal, the complex mol-ecules are stacked into columns along the b axis. In the columns, several inter-molecular π-π inter-actions between the six-membered rings are present, the shortest ring centroid-centroid distance being 3.733 (5) Å between pyridine rings.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 May</publication><modification>2025-04-04T14:12:11.738Z</modification><creation>2019-03-27T00:53:04Z</creation></dates><accession>S-EPMC3344296</accession><cross_references><pubmed>22590062</pubmed><doi>10.1107/S1600536812013608</doi></cross_references></HashMap>