{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 5)"],"submitter":["Si Y"],"pubmed_abstract":["In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa-hedral environment. Intra-molecular O-H⋯O hydrogen-bonding inter-actions and inter-molecular C-H⋯O hydrogen-bonding inter-actions are present in the structure. Adjacent mol-ecules pack along [100] through van der Waals forces."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m554"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344309"],"repository":["biostudies-literature"],"pubmed_title":["Bis(acetato-κO)bis-(pyridine-2-aldoxime-κ(2)N,N')nickel(II)."],"pmcid":["PMC3344309"],"pubmed_authors":["Si Y"],"additional_accession":[]},"is_claimable":false,"name":"Bis(acetato-κO)bis-(pyridine-2-aldoxime-κ(2)N,N')nickel(II).","description":"In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa-hedral environment. Intra-molecular O-H⋯O hydrogen-bonding inter-actions and inter-molecular C-H⋯O hydrogen-bonding inter-actions are present in the structure. Adjacent mol-ecules pack along [100] through van der Waals forces.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 May","modification":"2025-04-04T14:12:17.045Z","creation":"2019-03-27T00:53:05Z"},"accession":"S-EPMC3344309","cross_references":{"pubmed":["22590075"],"doi":["10.1107/S1600536812014377"]}}