{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 5)"],"submitter":["Gao L"],"pubmed_abstract":["The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an η(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [120.8 (6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2 (9)°; Zhang et al. (2003 ▶). Inorg. Chem.42, 633-640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro-methane solvent mol-ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47 (2)."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m560"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344313"],"repository":["biostudies-literature"],"pubmed_title":["[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-κ(2)P,P'](η(5)-cyclo-penta-dien-yl)(dicyanamido-κN)ruthenium(II) dichloro-methane monosolvate."],"pmcid":["PMC3344313"],"pubmed_authors":["Gao L"],"additional_accession":[]},"is_claimable":false,"name":"[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-κ(2)P,P'](η(5)-cyclo-penta-dien-yl)(dicyanamido-κN)ruthenium(II) dichloro-methane monosolvate.","description":"The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an η(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [120.8 (6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2 (9)°; Zhang et al. (2003 ▶). Inorg. Chem.42, 633-640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro-methane solvent mol-ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47 (2).","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 May","modification":"2025-04-04T14:12:18.423Z","creation":"2019-03-27T00:53:05Z"},"accession":"S-EPMC3344313","cross_references":{"pubmed":["22590079"],"doi":["10.1107/S1600536812014274"]}}