{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 5)"],"submitter":["Zheng SM"],"pubmed_abstract":["The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-mol-ecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent mol-ecules, the Ni(II) ion displays a compressed octa-hedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni-N distance of 2.119 (11) Å, and two axial N atoms from two NCS(-) anions, with a mean Ni-N distance of 2.079 (7) Å. The crystal packing exhibits weak inter-molecular S⋯S contacts of 3.411 (2) Å."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m623"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344356"],"repository":["biostudies-literature"],"pubmed_title":["Tetra-kis(1-phenyl-1H-imidazole-κN(3))bis-(thio-cyanato-κN)nickel(II)."],"pmcid":["PMC3344356"],"pubmed_authors":["Zheng SM","Liu BC"],"additional_accession":[]},"is_claimable":false,"name":"Tetra-kis(1-phenyl-1H-imidazole-κN(3))bis-(thio-cyanato-κN)nickel(II).","description":"The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-mol-ecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent mol-ecules, the Ni(II) ion displays a compressed octa-hedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni-N distance of 2.119 (11) Å, and two axial N atoms from two NCS(-) anions, with a mean Ni-N distance of 2.079 (7) Å. The crystal packing exhibits weak inter-molecular S⋯S contacts of 3.411 (2) Å.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 May","modification":"2025-04-04T14:12:34.692Z","creation":"2019-03-27T00:53:05Z"},"accession":"S-EPMC3344356","cross_references":{"pubmed":["22590122"],"doi":["10.1107/S1600536812015437"]}}