<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 5)</volume><submitter>Shirvan SA</submitter><pubmed_abstract>In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol-ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa-hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (-) anions link to the chain via O-H⋯O and N-H⋯O hydrogen bonding. Weak inter-molecular C-H⋯O inter-actions also occur.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m627-8</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344359</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>catena-Poly[[[aqua-(pyrazine-2-carboxamide-κ(2)N(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)] dinitrate].</pubmed_title><pmcid>PMC3344359</pmcid><pubmed_authors>Haydari Dezfuli S</pubmed_authors><pubmed_authors>Shirvan SA</pubmed_authors></additional><is_claimable>false</is_claimable><name>catena-Poly[[[aqua-(pyrazine-2-carboxamide-κ(2)N(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)] dinitrate].</name><description>In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol-ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa-hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (-) anions link to the chain via O-H⋯O and N-H⋯O hydrogen bonding. Weak inter-molecular C-H⋯O inter-actions also occur.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 May</publication><modification>2025-04-04T14:12:35.78Z</modification><creation>2019-03-27T00:53:05Z</creation></dates><accession>S-EPMC3344359</accession><cross_references><pubmed>22590125</pubmed><doi>10.1107/S1600536812016017</doi></cross_references></HashMap>