{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 5)"],"submitter":["Fonseca Ade S"],"pubmed_abstract":["The reaction of cadmium acetate dihydrate with 2-acetyl-pyridine (4-phenyl-thio-semicarbazone) yielded the title compound, [Cd(C(14)H(13)N(4)S)(2)]. The Cd(II) atom is six-coordin-ated in a distorted octa-hedral environment by two deproton-ated thio-semicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, mol-ecules are connected through inversion centers via pairs of N-H⋯S inter-actions, building a one-dimensional hydrogen-bonded polymer along [0-1-1]."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m635-6"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344363"],"repository":["biostudies-literature"],"pubmed_title":["Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl-idene]thio-semicarbazidato-κ(2)N(1),S}cadmium."],"pmcid":["PMC3344363"],"pubmed_authors":["Fonseca Ade S","Gervini VC","Bresolin L","de Oliveira AB","Locatelli A"],"additional_accession":[]},"is_claimable":false,"name":"Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl-idene]thio-semicarbazidato-κ(2)N(1),S}cadmium.","description":"The reaction of cadmium acetate dihydrate with 2-acetyl-pyridine (4-phenyl-thio-semicarbazone) yielded the title compound, [Cd(C(14)H(13)N(4)S)(2)]. The Cd(II) atom is six-coordin-ated in a distorted octa-hedral environment by two deproton-ated thio-semicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, mol-ecules are connected through inversion centers via pairs of N-H⋯S inter-actions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 May","modification":"2025-04-04T14:12:37.42Z","creation":"2019-03-27T00:53:05Z"},"accession":"S-EPMC3344363","cross_references":{"pubmed":["22590129"],"doi":["10.1107/S1600536812016558"]}}