<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 5)</volume><submitter>Li YF</submitter><pubmed_abstract>In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxyl-ate groups of two different furan-2,5-dicarboxyl-ate dianions. The geometry of the Cu(2+) ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. O(w)-H⋯O and N(i)-H⋯O (w = water and i = imidazole) hydrogen bonds help to establish the packing.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m659</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344379</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>catena-Poly[[[aqua-bis-(1H-imidazole-κN(3))copper(II)]-μ-furan-2,5-di-car-boxylato-κ(2)O(2):O(5)] trihydrate].</pubmed_title><pmcid>PMC3344379</pmcid><pubmed_authors>Gao Y</pubmed_authors><pubmed_authors>Qin XL</pubmed_authors><pubmed_authors>Gao WY</pubmed_authors><pubmed_authors>Li YF</pubmed_authors><pubmed_authors>Xu Y</pubmed_authors></additional><is_claimable>false</is_claimable><name>catena-Poly[[[aqua-bis-(1H-imidazole-κN(3))copper(II)]-μ-furan-2,5-di-car-boxylato-κ(2)O(2):O(5)] trihydrate].</name><description>In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxyl-ate groups of two different furan-2,5-dicarboxyl-ate dianions. The geometry of the Cu(2+) ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. O(w)-H⋯O and N(i)-H⋯O (w = water and i = imidazole) hydrogen bonds help to establish the packing.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 May</publication><modification>2025-04-04T14:12:43.03Z</modification><creation>2019-03-27T00:53:05Z</creation></dates><accession>S-EPMC3344379</accession><cross_references><pubmed>22590145</pubmed><doi>10.1107/S1600536812016856</doi></cross_references></HashMap>