{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 5)"],"submitter":["Wang GX"],"pubmed_abstract":["In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O',O''-chelated by two symmetry-related 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ate anions in a distorted octa-hedral geometry. The 2-amino-benzothia-zol-3-ium cation links with the Ni complex anion via N-H⋯O hydrogen bonding. Extensive O-H⋯O and N-H⋯O hydrogen bonds involving the lattice water mol-ecules also occur in the crystal structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m683"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344403"],"repository":["biostudies-literature"],"pubmed_title":["Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate."],"pmcid":["PMC3344403"],"pubmed_authors":["Zhang F","Wang GX","Zhang QW"],"additional_accession":[]},"is_claimable":false,"name":"Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate.","description":"In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O',O''-chelated by two symmetry-related 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ate anions in a distorted octa-hedral geometry. The 2-amino-benzothia-zol-3-ium cation links with the Ni complex anion via N-H⋯O hydrogen bonding. Extensive O-H⋯O and N-H⋯O hydrogen bonds involving the lattice water mol-ecules also occur in the crystal structure.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 May","modification":"2025-04-04T14:12:51.024Z","creation":"2019-03-27T00:53:05Z"},"accession":"S-EPMC3344403","cross_references":{"pubmed":["22590165"],"doi":["10.1107/S1600536812017722"]}}