biostudies-literatureUnknown68(Pt 5)Wang GXIn the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O',O''-chelated by two symmetry-related 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ate anions in a distorted octa-hedral geometry. The 2-amino-benzothia-zol-3-ium cation links with the Ni complex anion via N-H⋯O hydrogen bonding. Extensive O-H⋯O and N-H⋯O hydrogen bonds involving the lattice water mol-ecules also occur in the crystal structure.Acta crystallographica. Section E, Structure reports onlinem683https://www.ebi.ac.uk/biostudies/studies/S-EPMC3344403biostudies-literatureBis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate.PMC3344403Zhang FWang GXZhang QWfalseBis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate.In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O',O''-chelated by two symmetry-related 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ate anions in a distorted octa-hedral geometry. The 2-amino-benzothia-zol-3-ium cation links with the Ni complex anion via N-H⋯O hydrogen bonding. Extensive O-H⋯O and N-H⋯O hydrogen bonds involving the lattice water mol-ecules also occur in the crystal structure.2012-01-01T00:00:00Z2012 May2025-04-04T14:12:51.024Z2019-03-27T00:53:05ZS-EPMC33444032259016510.1107/S1600536812017722