biostudies-literatureKrasovskiy ANIGMS NIH HHS3818-21https://www.ebi.ac.uk/biostudies/studies/S-EPMC3365518biostudies-literatureUnknown13(15)Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly improves yields of Negishi couplings in general.Organic lettersLigand effects on Negishi couplings of alkenyl halides.PMC3365518R01 GM086485Krasovskiy ALipshutz BHfalseLigand effects on Negishi couplings of alkenyl halides.Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly improves yields of Negishi couplings in general.2011-01-01T00:00:00Z2011 Aug2025-04-04T23:29:45.603Z2019-03-27T00:54:03ZS-EPMC33655182173994810.1021/ol2010165