{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 6)"],"submitter":["Yang L"],"pubmed_abstract":["The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m796"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379124"],"repository":["biostudies-literature"],"pubmed_title":["Tetra-μ(3)-iodido-tetra-kis-{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN(3)]copper(I)}."],"pmcid":["PMC3379124"],"pubmed_authors":["Yang L","Zhang Z"],"additional_accession":[]},"is_claimable":false,"name":"Tetra-μ(3)-iodido-tetra-kis-{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN(3)]copper(I)}.","description":"The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Jun","modification":"2025-04-05T13:00:21.52Z","creation":"2019-03-27T00:54:42Z"},"accession":"S-EPMC3379124","cross_references":{"pubmed":["22719345"],"doi":["10.1107/S160053681202257X"]}}