biostudies-literatureUnknown68(Pt 6)Shawkataly OBIn the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis-(di-o-tolyl-phosphan-yl)methane (dtpm) ligand bridges one of the Ru-Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].Acta crystallographica. Section E, Structure reports onlinem812-3https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379136biostudies-literature[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro-form disolvate.PMC3379136Fun HKSirat SSShawkataly OBKhan IAQuah CKfalse[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro-form disolvate.In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis-(di-o-tolyl-phosphan-yl)methane (dtpm) ligand bridges one of the Ru-Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].2012-01-01T00:00:00Z2012 Jun2025-04-05T13:00:24.299Z2019-03-27T00:54:42ZS-EPMC33791362271935710.1107/S1600536812023227