<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 6)</volume><submitter>Li XL</submitter><pubmed_abstract>The hydro-thermal reaction of Zn(CH(3)COO)(2), NaOH and l-cysteic acid produced the title compound, [Na(2)Zn(C(3)H(5)NO(5)S)(2)](n). The Zn(II) cation is situated on an inversion centre and is in a distorted octa-hedral environment, being chelated by two deprotoned l-cysteic acid ligands through two amino N atoms and two carb-oxy-lic O atoms, with the two axial positions occupied by two carb-oxy-lic O atoms from two other l-cysteic acid ligands. Each l-cysteic acid ligand bridges five Na(I) ions via its sulfonate group and two Zn(II) ions via its carboxyl group, forming a three-dimensional framework. Weak N-H⋯O hydrogen bonding is observed in the crystal structure.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m849</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379187</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Poly[bis-(μ(7)-3-sulfonato-l-alaninato)sodiumzinc].</pubmed_title><pmcid>PMC3379187</pmcid><pubmed_authors>Liu L</pubmed_authors><pubmed_authors>Li XL</pubmed_authors><pubmed_authors>Yu J</pubmed_authors></additional><is_claimable>false</is_claimable><name>Poly[bis-(μ(7)-3-sulfonato-l-alaninato)sodiumzinc].</name><description>The hydro-thermal reaction of Zn(CH(3)COO)(2), NaOH and l-cysteic acid produced the title compound, [Na(2)Zn(C(3)H(5)NO(5)S)(2)](n). The Zn(II) cation is situated on an inversion centre and is in a distorted octa-hedral environment, being chelated by two deprotoned l-cysteic acid ligands through two amino N atoms and two carb-oxy-lic O atoms, with the two axial positions occupied by two carb-oxy-lic O atoms from two other l-cysteic acid ligands. Each l-cysteic acid ligand bridges five Na(I) ions via its sulfonate group and two Zn(II) ions via its carboxyl group, forming a three-dimensional framework. Weak N-H⋯O hydrogen bonding is observed in the crystal structure.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Jun</publication><modification>2025-04-05T13:00:33.039Z</modification><creation>2019-03-27T00:54:42Z</creation></dates><accession>S-EPMC3379187</accession><cross_references><pubmed>22719385</pubmed><doi>10.1107/S160053681202394X</doi></cross_references></HashMap>