<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 6)</volume><submitter>Tiritiris I</submitter><pubmed_abstract>The reaction of 3,3,3-tris-(dimethyl-amino)-1-phenyl-prop-1-yne with bromine in pentane yields the title compound, C(13)H(17)N(2) (+)·Br(-). The acetyl-enic bond distance [1.197 (2) Å] is consistent with a C C triple bond. The amidinium C=N bonds [1.325 (2) and 1.330 (2) Å] have double-bond character and the positive charge is delocalized between the two dimethyl-amino groups.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o1812</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379386</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>3-Phenyl-N,N,N',N'-tetra-methyl-1-ethyne-1-carboximidamidium bromide.</pubmed_title><pmcid>PMC3379386</pmcid><pubmed_authors>Kantlehner W</pubmed_authors><pubmed_authors>Tiritiris I</pubmed_authors></additional><is_claimable>false</is_claimable><name>3-Phenyl-N,N,N',N'-tetra-methyl-1-ethyne-1-carboximidamidium bromide.</name><description>The reaction of 3,3,3-tris-(dimethyl-amino)-1-phenyl-prop-1-yne with bromine in pentane yields the title compound, C(13)H(17)N(2) (+)·Br(-). The acetyl-enic bond distance [1.197 (2) Å] is consistent with a C C triple bond. The amidinium C=N bonds [1.325 (2) and 1.330 (2) Å] have double-bond character and the positive charge is delocalized between the two dimethyl-amino groups.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Jun</publication><modification>2025-04-05T12:59:44.429Z</modification><creation>2019-03-27T00:54:43Z</creation></dates><accession>S-EPMC3379386</accession><cross_references><pubmed>22719584</pubmed><doi>10.1107/S1600536812021873</doi></cross_references></HashMap>