{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 6)"],"submitter":["Jacob JM"],"pubmed_abstract":["The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol-ecules are linked through pairs of N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H⋯N, O-H⋯O and C-H⋯π inter-actions are also present."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["o1871-2"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379435"],"repository":["biostudies-literature"],"pubmed_title":["(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide."],"pmcid":["PMC3379435"],"pubmed_authors":["Jacob JM","Sithambaresan M","Kurup MR"],"additional_accession":[]},"is_claimable":false,"name":"(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide.","description":"The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol-ecules are linked through pairs of N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H⋯N, O-H⋯O and C-H⋯π inter-actions are also present.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Jun","modification":"2025-04-05T12:59:55.94Z","creation":"2019-03-27T00:54:44Z"},"accession":"S-EPMC3379435","cross_references":{"pubmed":["22719633"],"doi":["10.1107/S1600536812022520"]}}