<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 6)</volume><submitter>Jacob JM</submitter><pubmed_abstract>The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol-ecules are linked through pairs of N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H⋯N, O-H⋯O and C-H⋯π inter-actions are also present.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o1871-2</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3379435</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide.</pubmed_title><pmcid>PMC3379435</pmcid><pubmed_authors>Jacob JM</pubmed_authors><pubmed_authors>Sithambaresan M</pubmed_authors><pubmed_authors>Kurup MR</pubmed_authors></additional><is_claimable>false</is_claimable><name>(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide.</name><description>The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol-ecules are linked through pairs of N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H⋯N, O-H⋯O and C-H⋯π inter-actions are also present.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Jun</publication><modification>2025-04-05T12:59:55.94Z</modification><creation>2019-03-27T00:54:44Z</creation></dates><accession>S-EPMC3379435</accession><cross_references><pubmed>22719633</pubmed><doi>10.1107/S1600536812022520</doi></cross_references></HashMap>