{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ge P"],"funding":["Swiss National Science Foundation","European Research Council"],"pagination":["11558-63"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3406862"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["109(29)"],"pubmed_abstract":["The photochemical reactivity of osmocene in a biphasic water-organic solvent system has been investigated to probe its water splitting properties. The photoreduction of aqueous protons to hydrogen under anaerobic conditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the osmocenium metal-metal dimer formed during H(2) production were studied by electrochemical methods, UV-visible spectrometry, gas chromatography, and nuclear magnetic resonance spectroscopy. Density functional theory computations were used to validate the reaction pathways."],"journal":["Proceedings of the National Academy of Sciences of the United States of America"],"pubmed_title":["Biphasic water splitting by osmocene."],"pmcid":["PMC3406862"],"funding_grant_id":["121577","200021","257096"],"pubmed_authors":["Corminboeuf C","Olaya AJ","Girault HH","Todorova TK","Mendez M","Hu X","Patir IH","Vrubel H","Ge P"],"additional_accession":[]},"is_claimable":false,"name":"Biphasic water splitting by osmocene.","description":"The photochemical reactivity of osmocene in a biphasic water-organic solvent system has been investigated to probe its water splitting properties. The photoreduction of aqueous protons to hydrogen under anaerobic conditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the osmocenium metal-metal dimer formed during H(2) production were studied by electrochemical methods, UV-visible spectrometry, gas chromatography, and nuclear magnetic resonance spectroscopy. Density functional theory computations were used to validate the reaction pathways.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Jul","modification":"2025-04-19T02:53:40.446Z","creation":"2019-03-27T00:56:03Z"},"accession":"S-EPMC3406862","cross_references":{"pubmed":["22665787"],"doi":["10.1073/pnas.1203743109"]}}