{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 10)"],"submitter":["Golenya IA"],"pubmed_abstract":["In the title compound, [Co(C(10)H(8)N(2))(3)][Co(C(7)H(3)NO(4))(2)](2)(ClO(4))·0.5C(3)H(7)NO·1.3H(2)O, the Co(III) atom in the complex cation is pseudoocta-hedrally coordinated by six N atoms of three chelating bipyridine ligands. The Co(III) atom in the complex anion is coordinated by two pyridine N atoms and four carboxyl-ate O atoms of two doubly deprotonated pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. One dimethyl-formamide solvent mol-ecule and two water mol-ecules are half-occupied and one water mol-ecule is 0.3-occupied. O-H⋯O hydrogen bonds link the water mol-ecules, the perchlorate anions and the complex anions. π-π inter-actions between the pyridine rings of the complex anions are also observed [centroid-centroid distance = 3.804 (3) Å]."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1237-8"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3470129"],"repository":["biostudies-literature"],"pubmed_title":["Tris(2,2'-bipyridine-κ(2)N,N')cobalt(III) bis-[bis-(pyridine-2,6-dicarboxyl-ato-κ(3)O(2),N,O(6))cobaltate(III)] perchlorate dimethyl-formamide hemisolvate 1.3-hydrate."],"pmcid":["PMC3470129"],"pubmed_authors":["Iskenderov TS","Kotova NV","Golenya IA","Boyko AN","Haukka M"],"additional_accession":[]},"is_claimable":false,"name":"Tris(2,2'-bipyridine-κ(2)N,N')cobalt(III) bis-[bis-(pyridine-2,6-dicarboxyl-ato-κ(3)O(2),N,O(6))cobaltate(III)] perchlorate dimethyl-formamide hemisolvate 1.3-hydrate.","description":"In the title compound, [Co(C(10)H(8)N(2))(3)][Co(C(7)H(3)NO(4))(2)](2)(ClO(4))·0.5C(3)H(7)NO·1.3H(2)O, the Co(III) atom in the complex cation is pseudoocta-hedrally coordinated by six N atoms of three chelating bipyridine ligands. The Co(III) atom in the complex anion is coordinated by two pyridine N atoms and four carboxyl-ate O atoms of two doubly deprotonated pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. One dimethyl-formamide solvent mol-ecule and two water mol-ecules are half-occupied and one water mol-ecule is 0.3-occupied. O-H⋯O hydrogen bonds link the water mol-ecules, the perchlorate anions and the complex anions. π-π inter-actions between the pyridine rings of the complex anions are also observed [centroid-centroid distance = 3.804 (3) Å].","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Oct","modification":"2025-04-19T15:54:23.495Z","creation":"2019-03-27T00:59:00Z"},"accession":"S-EPMC3470129","cross_references":{"pubmed":["23125573"],"doi":["10.1107/S1600536812037208"]}}