<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>68(Pt 11)</volume><submitter>Kim TH</submitter><pubmed_abstract>IN THE TITLE COMPOUND [SYSTEMATIC NAME: (3-chloro-2,6-dimeth-oxy-phen-yl)(eth-oxy-imino)-methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro-dimeth-oxy-phenyl rings are linked by the eth-oxy-imino-methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C-H⋯O and C-H⋯Cl hydrogen bonds between the phenyl and chloro-dimeth-oxy-phenyl rings generate R(2) (2)(8) rings which link the mol-ecules into zigzag chains along the b axis. Additional C-H⋯O contacts, together with weak inter-molecular C-H⋯π inter-actions, further link the mol-ecules into a three-dimensional network.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o3237</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3515316</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Benzoximate.</pubmed_title><pmcid>PMC3515316</pmcid><pubmed_authors>Kim TH</pubmed_authors><pubmed_authors>Park KM</pubmed_authors><pubmed_authors>Kim J</pubmed_authors><pubmed_authors>Moon SH</pubmed_authors></additional><is_claimable>false</is_claimable><name>Benzoximate.</name><description>IN THE TITLE COMPOUND [SYSTEMATIC NAME: (3-chloro-2,6-dimeth-oxy-phen-yl)(eth-oxy-imino)-methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro-dimeth-oxy-phenyl rings are linked by the eth-oxy-imino-methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C-H⋯O and C-H⋯Cl hydrogen bonds between the phenyl and chloro-dimeth-oxy-phenyl rings generate R(2) (2)(8) rings which link the mol-ecules into zigzag chains along the b axis. Additional C-H⋯O contacts, together with weak inter-molecular C-H⋯π inter-actions, further link the mol-ecules into a three-dimensional network.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Nov</publication><modification>2025-04-04T19:08:44.281Z</modification><creation>2019-03-27T01:01:30Z</creation></dates><accession>S-EPMC3515316</accession><cross_references><pubmed>23284536</pubmed><doi>10.1107/S1600536812044248</doi></cross_references></HashMap>