<HashMap><database>biostudies-literature</database><scores/><additional><submitter>Liao YX</submitter><funding>NIGMS NIH HHS</funding><pagination>5897-5901</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3547403</full_dataset_link><repository>biostudies-literature</repository><omics_type>Unknown</omics_type><volume>2012(30)</volume><pubmed_abstract>Tandem aldol condensation of aldehydes with methyl ketones followed by anionic four-electron donor-based (Type I) platinacycle-catalyzed addition reactions of arylboronic acids to form β-arylated ketones is described. Good to excellent yields of β-arylated ketones were obtained for the tandem reactions of aromatic/aliphatic aldehydes, methyl ketones and arylboronic acids, and moderate yields were observed for the tandem reaction with α, β-unsaturated aldehydes as the aldehyde source.</pubmed_abstract><journal>European journal of organic chemistry</journal><pubmed_title>Tandem Aldol Condensation - Platinacycle-Catalyzed Addition Reactions of Aldehydes, Methyl Ketones and Arylboronic Acids.</pubmed_title><pmcid>PMC3547403</pmcid><funding_grant_id>R15 GM094709</funding_grant_id><pubmed_authors>Liao YX</pubmed_authors><pubmed_authors>Hu QS</pubmed_authors></additional><is_claimable>false</is_claimable><name>Tandem Aldol Condensation - Platinacycle-Catalyzed Addition Reactions of Aldehydes, Methyl Ketones and Arylboronic Acids.</name><description>Tandem aldol condensation of aldehydes with methyl ketones followed by anionic four-electron donor-based (Type I) platinacycle-catalyzed addition reactions of arylboronic acids to form β-arylated ketones is described. Good to excellent yields of β-arylated ketones were obtained for the tandem reactions of aromatic/aliphatic aldehydes, methyl ketones and arylboronic acids, and moderate yields were observed for the tandem reaction with α, β-unsaturated aldehydes as the aldehyde source.</description><dates><release>2012-01-01T00:00:00Z</release><publication>2012 Oct</publication><modification>2025-04-04T01:06:30.484Z</modification><creation>2019-03-27T01:03:24Z</creation></dates><accession>S-EPMC3547403</accession><cross_references><pubmed>23335856</pubmed><doi>10.1002/ejoc.201200867</doi></cross_references></HashMap>