{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["68(Pt 12)"],"submitter":["Liu H"],"pubmed_abstract":["In the title compound, [Zn2(C8H4O6)(C12H8N2)2(H2O)6](C8H4O6), the complete ions of both the binuclear dication and the dianion are generated by crystallographic inversion symmetry. The Zn atom is bonded to an N,N'-bidentate phenanthroline ligand, three water moleules and an O-mono-denate 2,5-dihy-droxy-terephthalate dianion. In the resulting distorted octa-hedral ZnN2O4 coordination poly-hedron, the water O atoms are in a mer orientation. Two intra-molecular O-H⋯O hydrogen bonds occur in the bridging 2,5-dihy-droxy-terephthalate dianion within the complex cation and also in the free dianion. An intra-molecular Ow-H⋯O (w = water) hydrogen bond also occurs within the dication. In the crystal, O-H⋯O hydrogen bonds link the component ions into a three-dimensional network."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1503-4"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3588754"],"repository":["biostudies-literature"],"pubmed_title":["μ-2,5-Dihy-droxy-terephthalato-bis-[tri-aqua-(1,10-phenanthroline)zinc] dihy-droxy-terephthalate."],"pmcid":["PMC3588754"],"pubmed_authors":["Liu H","Zhang AP","Liu B","Li CB"],"additional_accession":[]},"is_claimable":false,"name":"μ-2,5-Dihy-droxy-terephthalato-bis-[tri-aqua-(1,10-phenanthroline)zinc] dihy-droxy-terephthalate.","description":"In the title compound, [Zn2(C8H4O6)(C12H8N2)2(H2O)6](C8H4O6), the complete ions of both the binuclear dication and the dianion are generated by crystallographic inversion symmetry. The Zn atom is bonded to an N,N'-bidentate phenanthroline ligand, three water moleules and an O-mono-denate 2,5-dihy-droxy-terephthalate dianion. In the resulting distorted octa-hedral ZnN2O4 coordination poly-hedron, the water O atoms are in a mer orientation. Two intra-molecular O-H⋯O hydrogen bonds occur in the bridging 2,5-dihy-droxy-terephthalate dianion within the complex cation and also in the free dianion. An intra-molecular Ow-H⋯O (w = water) hydrogen bond also occurs within the dication. In the crystal, O-H⋯O hydrogen bonds link the component ions into a three-dimensional network.","dates":{"release":"2012-01-01T00:00:00Z","publication":"2012 Dec","modification":"2025-04-21T23:41:36.817Z","creation":"2019-03-27T01:05:38Z"},"accession":"S-EPMC3588754","cross_references":{"pubmed":["23468719"],"doi":["10.1107/S1600536812045837"]}}