{"database":"biostudies-literature","file_versions":[],"scores":{"citationCount":0,"reanalysisCount":0,"viewCount":44,"searchCount":0},"additional":{"submitter":["Olivares-Romero JL"],"funding":["NIGMS NIH HHS"],"pagination":["3411-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3625140"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["135(9)"],"pubmed_abstract":["An efficient and versatile method for the enantioselective epoxidation of both tertiary allylic and homoallylic alcohols catalyzed by Hf(IV)-bishydroxamic acid (BHA) complexes is described. Asymmetric epoxidation, kinetic resolution, and desymmetrization have been developed, demonstrating the flexible nature of the Hf(IV)-BHA system. This is the first report in which these substrates were obtained with enantioselectivities of up to 99%."],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Catalytic enantioselective epoxidation of tertiary allylic and homoallylic alcohols."],"pmcid":["PMC3625140"],"funding_grant_id":["R01 GM068433","2R01GM068433"],"pubmed_authors":["Li Z","Yamamoto H","Olivares-Romero JL"],"view_count":["44"],"additional_accession":[]},"is_claimable":false,"name":"Catalytic enantioselective epoxidation of tertiary allylic and homoallylic alcohols.","description":"An efficient and versatile method for the enantioselective epoxidation of both tertiary allylic and homoallylic alcohols catalyzed by Hf(IV)-bishydroxamic acid (BHA) complexes is described. Asymmetric epoxidation, kinetic resolution, and desymmetrization have been developed, demonstrating the flexible nature of the Hf(IV)-BHA system. This is the first report in which these substrates were obtained with enantioselectivities of up to 99%.","dates":{"release":"2013-01-01T00:00:00Z","publication":"2013 Mar","modification":"2024-11-21T05:54:28.346Z","creation":"2019-03-26T23:30:03Z"},"accession":"S-EPMC3625140","cross_references":{"pubmed":["23406082"],"doi":["10.1021/ja401182a"]}}