{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Kumar NN"],"funding":["NIGMS NIH HHS"],"pagination":["9608-11"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3763736"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["135(26)"],"pubmed_abstract":["Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts. This expeditious access to structurally unprecedented polyheterocyclic cores is being developed in the context of diversity-oriented synthesis, as the modular design allows for rapid \"pre-assembly\" of diverse photoprecursors from simple building blocks/diversity inputs."],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Photoassisted synthesis of enantiopure alkaloid mimics possessing unprecedented polyheterocyclic cores."],"pmcid":["PMC3763736"],"funding_grant_id":["GM-093930","R15 GM093930"],"pubmed_authors":["Kumar NN","Mukhina OA","Kutateladze AG"],"additional_accession":[]},"is_claimable":false,"name":"Photoassisted synthesis of enantiopure alkaloid mimics possessing unprecedented polyheterocyclic cores.","description":"Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts. This expeditious access to structurally unprecedented polyheterocyclic cores is being developed in the context of diversity-oriented synthesis, as the modular design allows for rapid \"pre-assembly\" of diverse photoprecursors from simple building blocks/diversity inputs.","dates":{"release":"2013-01-01T00:00:00Z","publication":"2013 Jul","modification":"2025-04-04T09:40:45.483Z","creation":"2019-03-26T23:30:06Z"},"accession":"S-EPMC3763736","cross_references":{"pubmed":["23789841"],"doi":["10.1021/ja4042109"]}}