{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Chung WJ"],"funding":["NIGMS NIH HHS"],"pagination":["10052-5"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3835569"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["52(38)"],"pubmed_abstract":["Magnificent seven: The chlorosulfolipid mytilipin A was synthesized in racemic form in seven steps and in enantioenriched form in eight steps. Key transformations include a highly diastereoselective bromoallylation of a sensitive α,β-dichloroaldehyde, a kinetic resolution of a vinyl epoxide, a convergent and highly Z-selective alkene cross-metathesis, and a chemoselective and diastereoselective dichlorination of a complex diene."],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["A synthesis of the chlorosulfolipid mytilipin A via a longest linear sequence of seven steps."],"pmcid":["PMC3835569"],"funding_grant_id":["R01 GM086483"],"pubmed_authors":["Chung WJ","Bedke DK","Carlson JS","Vanderwal CD"],"additional_accession":[]},"is_claimable":false,"name":"A synthesis of the chlorosulfolipid mytilipin A via a longest linear sequence of seven steps.","description":"Magnificent seven: The chlorosulfolipid mytilipin A was synthesized in racemic form in seven steps and in enantioenriched form in eight steps. Key transformations include a highly diastereoselective bromoallylation of a sensitive α,β-dichloroaldehyde, a kinetic resolution of a vinyl epoxide, a convergent and highly Z-selective alkene cross-metathesis, and a chemoselective and diastereoselective dichlorination of a complex diene.","dates":{"release":"2013-01-01T00:00:00Z","publication":"2013 Sep","modification":"2025-04-04T12:26:43.144Z","creation":"2019-03-27T03:09:02Z"},"accession":"S-EPMC3835569","cross_references":{"pubmed":["23929596"],"doi":["10.1002/anie.201304565"]}}