<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>69(Pt 9)</volume><submitter>Suhitha S</submitter><pubmed_abstract>In the title compound, [Fe(C5H5)(C33H25BrN3O)], the fused four-ring system, 11H-indeno-[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087?(3)?Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76?(19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190?(9)?Å from the attached benzene ring. The mol-ecular structure features an intra-molecular C-H?N inter-action, which generates an S(8) ring motif. The crystal packing features C-H?O inter-actions, which generate R 2 (2)(18) centrosymmetric dimers, as well as C-H?? inter-actions.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m512-3</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3884418</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>2-(4-Bromo-benzo-yl)-1-ferrocenyl-spiro-[11H-pyrrolidizine-3,11'-indeno-[1,2-b]quinoxaline].</pubmed_title><pmcid>PMC3884418</pmcid><pubmed_authors>Raghunathan R</pubmed_authors><pubmed_authors>Velmurugan D</pubmed_authors><pubmed_authors>Gunasekaran K</pubmed_authors><pubmed_authors>Suhitha S</pubmed_authors><pubmed_authors>Sureshbabu AR</pubmed_authors></additional><is_claimable>false</is_claimable><name>2-(4-Bromo-benzo-yl)-1-ferrocenyl-spiro-[11H-pyrrolidizine-3,11'-indeno-[1,2-b]quinoxaline].</name><description>In the title compound, [Fe(C5H5)(C33H25BrN3O)], the fused four-ring system, 11H-indeno-[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087?(3)?Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76?(19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190?(9)?Å from the attached benzene ring. The mol-ecular structure features an intra-molecular C-H?N inter-action, which generates an S(8) ring motif. The crystal packing features C-H?O inter-actions, which generate R 2 (2)(18) centrosymmetric dimers, as well as C-H?? inter-actions.</description><dates><release>2013-01-01T00:00:00Z</release><publication>2013</publication><modification>2021-02-21T05:41:30Z</modification><creation>2019-03-27T01:19:35Z</creation></dates><accession>S-EPMC3884418</accession><cross_references><pubmed>24427003</pubmed><doi>10.1107/S1600536813023064</doi></cross_references></HashMap>