{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Greenfield JT"],"funding":["NCRR NIH HHS","NIGMS NIH HHS"],"pagination":["3162-9"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3989075"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["53(6)"],"pubmed_abstract":["Solvothermal synthesis was used to create a low-dimensional iron(II) chloride formate compound, NH4FeCl2(HCOO), that exhibits interesting magnetic properties. NH4FeCl2(HCOO) crystallizes in the monoclinic space group C2/c (No. 15) with a = 7.888(1) Å, b = 11.156(2) Å, c = 6.920(2) Å, and β = 108.066(2)°. The crystal structure consists of infinite zigzag chains of distorted Fe(2+)-centered octahedra linked by μ2-Cl and syn-syn formate bridges, with interchain hydrogen bonding through NH4(+) cations holding the chains together. The unique Fe(2+) site is coordinated by four equatorial chlorides at a distance of 2.50 Å and two axial oxygens at a distance of 2.08 Å. Magnetic measurements performed on powder and oriented single-crystal samples show complex anisotropic magnetic behavior dominated"],"journal":["Inorganic chemistry"],"pubmed_title":["NH4FeCl2(HCOO): synthesis, structure, and magnetism of a novel low-dimensional magnetic material."],"pmcid":["PMC3989075"],"funding_grant_id":["R01 GM065440","S10 RR023656","1S10RR023656-01A1"],"pubmed_authors":["Kamali S","Chen M","Kovnir K","Izquierdo N","Greenfield JT"],"additional_accession":[]},"is_claimable":false,"name":"NH4FeCl2(HCOO): synthesis, structure, and magnetism of a novel low-dimensional magnetic material.","description":"Solvothermal synthesis was used to create a low-dimensional iron(II) chloride formate compound, NH4FeCl2(HCOO), that exhibits interesting magnetic properties. NH4FeCl2(HCOO) crystallizes in the monoclinic space group C2/c (No. 15) with a = 7.888(1) Å, b = 11.156(2) Å, c = 6.920(2) Å, and β = 108.066(2)°. The crystal structure consists of infinite zigzag chains of distorted Fe(2+)-centered octahedra linked by μ2-Cl and syn-syn formate bridges, with interchain hydrogen bonding through NH4(+) cations holding the chains together. The unique Fe(2+) site is coordinated by four equatorial chlorides at a distance of 2.50 Å and two axial oxygens at a distance of 2.08 Å. Magnetic measurements performed on powder and oriented single-crystal samples show complex anisotropic magnetic behavior dominated","dates":{"release":"2014-01-01T00:00:00Z","publication":"2014 Mar","modification":"2025-04-05T10:45:41.738Z","creation":"2019-03-27T01:25:10Z"},"accession":"S-EPMC3989075","cross_references":{"pubmed":["24571410"],"doi":["10.1021/ic403173v"]}}