biostudies-literatureLevin MDNIGMS NIH HHS6211-5https://www.ebi.ac.uk/biostudies/studies/S-EPMC4076148biostudies-literatureUnknown53(24)A sp(3)-sp(2) C-C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C-Br oxidative addition, and C-C reductive elimination in a model gold complex are shown. We expect that this method will serve as a platform for the development of novel transformations involving redox-active gold catalysts.Angewandte Chemie (International ed. in English)Gold-catalyzed allylation of aryl boronic acids: accessing cross-coupling reactivity with gold.PMC4076148R01 GM073932Levin MDToste FDfalseGold-catalyzed allylation of aryl boronic acids: accessing cross-coupling reactivity with gold.A sp(3)-sp(2) C-C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C-Br oxidative addition, and C-C reductive elimination in a model gold complex are shown. We expect that this method will serve as a platform for the development of novel transformations involving redox-active gold catalysts.2014-01-01T00:00:00Z2014 Jun2025-04-04T10:08:55.536Z2019-03-27T01:31:05ZS-EPMC40761482479913210.1002/anie.201402924